Thermophysical Properties of Pure Fluids and Aqueous Systems at High Temperatures and High Pressures

ISBN
1-56700-212-9

An enormous amount of heretofore unavailable data has been collected and presented in this large volume. The data covers thermal, caloric and transport properties for aqueous systems: light and heavy water, their mixtures, hydrocarbons, alcohols, aqueous salts, aqueous hydrocarbons and aqueous alcohol solutions – all at high and critical parameters. Experimental data, instrumentation, data analysis and methods of measurement are given and analyzed.
This book is designed for specialists in molecular physics, chemical technology and chemical and power engineering, as well as researchers, lecturers, postgraduates and students in technical colleges and universities.

1350 pages, ©2005

THERMOPHYSICAL PROPERTIES OF PURE FLUIDS AND AQUEOUS SYSTEMS AT HIGH TEMPERATURES AND HIGH PRESSURES / **1 Volumetric (PVTx) Properties of Pure Fluids and Aqueous Systems at High Temperatures and High Pressures, Including Near-Critical and Supercritical Conditions**

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1 Volumetric (PVTx) Properties of Pure Fluids and Aqueous Systems at High Temperatures and High Pressures, Including Near-Critical and Supercritical Conditions

1.1 Review of Available PVT Measurements for Light and Heavy Water, Pure Hydrocarbons, and Pure Methanol in the Near-Critical and Supercritical Conditions

1.1.1 Experimental PVT Data for Pure H₂O and D₂O in the Near-Critical and Supercritical Conditions

1.1.2 Experimental PVT Data for Pure Hydrocarbons in the Near-Critical and Supercritical Conditions

1.1.3 Saturated Liquid and Vapor Densities of Pure Light and Heavy Water. Experimental and Correlations

1.1.4 Saturated Liquid and Vapor Densities of Pure Hydrocarbons and Methanol. Experimental and Correlations

1.1.5 Vapor-Pressure Data for Pure Light and Heavy Water. Experimental and Correlations

1.1.6 Vapor-Pressure Data for Pure Hydrocarbons and Methanol. Experimental and Correlations

1.2 Review of Available PVTx Measurements for Near-Critical and Supercritical Aqueous Solutions. Phase Diagrams

1.2.1 Experimental Thermodynamic Data for H₂O + D₂O Mixtures

1.2.2 Thermodynamic Properties of Aqueous Hydrocarbon Mixtures in the Near-Critical and Supercritical Conditions

1.2.3 PVTx Properties of Aqueous Salt Solutions in Near-Critical and Supercritical Conditions

1.2.4 Saturated Liquid and Vapor Densities of 0.5H₂O + 0.5D₂O Mixtures

1.2.5 Saturated Liquid and Vapor Densities of Aqueous Hydrocarbon Mixtures

1.2.6 Saturated Liquid and Vapor Densities for Aqueous Salt Solutions

1.2.7 Vapor-Pressure Data for Aqueous Hydrocarbon Mixtures. Phase Diagrams

1.2.8 Vapor-Pressure Data for Aqueous Salt Solutions. Phase Diagrams

1.3 Equations of State for Pure Fluids: Hydrocarbons and Light and Heavy Water

1.3.1 Fundamental Equation of State for Toluene

1.3.2 Nonanalytic Equation of State for Toluene

1.3.3 Tait-Type Equation of State for Toluene

1.3.4 Mamedov-Akhundov Equation of State for Toluene

1.3.5 Benedict-Webb-Rubin-Type Equation of State for Hydrocarbons

1.3.6 Bender Equation of State for Hydrocarbons

1.3.7 Multiparameter Equation of State for n-Alkanes

1.3.8 Virial Equation of State for n-Alkanes

1.3.9 Beattie-Bridgeman Equation of State for n-Heptane

1.3.10 Scaling Type Equation of State for Hydrocarbons near the Critical Point

1.3.11 Crossover Equations of State for Light and Heavy Water

1.3.12 Fundamental Equations of State for Light and Heavy Water (IAPWS-85 and IAPWS-95 Formulations)

1.4 Equations of State for Aqueous Solutions in the Critical and Supercritical Regions

1.4.1 Equations of State for Water + Hydrocarbon Mixtures

1.4.2 Crossover Equations of State for Aqueous Solutions near the Critical Points

1.4.3 Classical Pitzer's Equation of State for Aqueous Salt Solutions in the Critical Region

1.5 The Critical Properties of Pure Fluids and Binary Aqueous Systems

1.5.1 The Critical Properties of Pure Fluids: Light and Heavy Water, Hydrocarbons, and Alcohols

1.5.2 The Critical Properties of Binary Aqueous Systems

1.6 Method of Constant-Volume Piezometer for Measurements of Aqueous Systems at High Temperatures and High Pressures, Including Near-Critical and Supercritical Conditions

1.6.1 Experimental Apparatus and Procedures

1.6.2 The Results of PVT Measurements for Pure Fluids: Hydrocarbons, Methanol, Light and Heavy Water in the Supercritical Region

1.6.3 The Results of PVTx Measurements for Aqueous Systems in the Supercritical Region

1.6.4 Excess, Partial, and Apparent Molar Volumes for Water + Hydrocarbon and H₂O + D₂O Mixtures in the Near-Critical and Supercritical Conditions

1.6.5 Thermodynamic and Structural Properties of Dilute Aqueous Salt and Aqueous Hydrocarbon Mixtures near the Critical Point of Pure Water. The Krichevskii Parameter

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Thermophysical Properties of Pure Fluids and Aqueous Systems at High Temperatures and High Pressures

THERMOPHYSICAL PROPERTIES OF PURE FLUIDS AND AQUEOUS SYSTEMS AT HIGH TEMPERATURES AND HIGH PRESSURES / 1 Volumetric (PVTx) Properties of Pure Fluids and Aqueous Systems at High Temperatures and High Pressures, Including Near-Critical and Supercritical Conditions

THERMOPHYSICAL PROPERTIES OF PURE FLUIDS AND AQUEOUS SYSTEMS AT HIGH TEMPERATURES AND HIGH PRESSURES / **1 Volumetric (PVTx) Properties of Pure Fluids and Aqueous Systems at High Temperatures and High Pressures, Including Near-Critical and Supercritical Conditions**